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Отправлено: 14.02.17 06:00. Заголовок: METHANE-RELATED CARBONATE CEMENTS IN POCKMARKS OF THE NORTH SEA
METHANE-RELATED CARBONATE CEMENTS IN POCKMARKS OF THE NORTH SEA MARTIN HOVLAND Statoil P.O. Box 300 N-4001 Stavanger, Norway MICHAEL R. TALBOT Geological Deparlment A University of Bergen N-5014 Bergen, Norway HENNING QVALE Institute for Energy Technology P.O. Box 40 N-2007 Kjeller, Norway SNORRE OLAUSSEN AND LARS AASBERG Statoil P.O. Box 300 N-4001 Stavanger, Norway ABSTRACT: Some pockmarks on the Norwegian continental shelf contain patches of cemented sediment that can provide hardgrounds attractive to a variety of benthonic organisms. Detailed examination of a sandstone sample from a pockmark in Norwegian Block 25/7 in the North Sea has revealed the presence of Mg calcite and aragonite cements, some of the latter forming botryoids. All cement types are characterized by extremely light carbon isotopic compositions, with a mean 5t3C value of -56.1%o PDB, which shows that the cements contain carbonate produced by oxidation of bingenic methane. Oxidation occurred in both the oxic and anoxic diagenetie zones. Trace amounts of interstitial methane (mean 6~3C = -40.8%¢) and higher hydrocarbon gases (up to C0 with a C,/Co ratio of 0.855--0.874 in the pockmark sediments indicate that some thermogenic methane may be mixed with the biogenic gas.
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